Guluronic Acid
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Guluronic acid is a
uronic acid 300px, The Fischer projections of glucose and glucuronic acid">glucose.html" ;"title="Fischer projections of glucose">Fischer projections of glucose and glucuronic acid. Glucose's terminal carbon's primary alcohol group has been oxidized to a ...
monosaccharide Monosaccharides (from Greek ''monos'': single, '' sacchar'': sugar), also called simple sugars, are the simplest forms of sugar and the most basic units (monomers) from which all carbohydrates are built. They are usually colorless, water-solub ...
that may be derived from
gulose Gulose is an aldohexose sugar. It is a monosaccharide that is very rare in nature, but has been found in archaea, bacteria and eukaryotes. It also exists as a syrup with a sweet taste. It is soluble in water and slightly soluble in methanol ...
. -Guluronic acid is a C-3 epimer of -
galacturonic acid -Galacturonic acid is a sugar acid, an oxidized form of galactose, -galactose. It is the main component of pectin, in which it exists as the polymer polygalacturonic acid.Debra Mohnen "Pectin structure and biosynthesis" Current Opinion in Plant B ...
and a C-5 epimer of -
mannuronic acid Mannuronic acid is a uronic acid monosaccharide that can be derived from mannose. Along with -guluronic acid, -mannuronic acid is a component of alginic acid, a polysaccharide found predominantly in brown algae Brown algae (singular: alga), com ...
. Along with -mannuronic acid, -guluronic acid is a component of
alginic acid Alginic acid, also called algin, is a naturally occurring, edible polysaccharide found in brown algae. It is hydrophilic and forms a viscous gum when hydrated. With metals such as sodium and calcium, its salts are known as alginates. Its colou ...
, a polysaccharide found in
brown algae Brown algae (singular: alga), comprising the class Phaeophyceae, are a large group of multicellular algae, including many seaweeds located in colder waters within the Northern Hemisphere. Brown algae are the major seaweeds of the temperate and po ...
. α-L-Guluronic acid has been found to bind divalent metal ions (such as calcium and strontium) through the carboxylate moiety and through the ''axial''-''equatorial''-''axial'' arrangement of hydroxyl groups found around the ring.


References

Uronic acids {{organic-compound-stub